Title

Reactivity of a Phosphaalkyne with Pentaarylboroles

Document Type

Article

Publication Date

4-2016

Publication Details

This article was originally published as:

Barnard, J. H., Yruegas, S., Couchman, S. A., Wilson, D. J., Dutton, J. L., & Martin, C. D. (2016). Reactivity of a phosphaalkyne with pentaarylboroles. Organometallics, 35(7), 929-931. doi:10.1021/acs.organomet.6b00123

ISSN: 0276-7333

Abstract

The reactions of pentaarylboroles with 1-adamantylphosphaalkyne led to the formation of unique 1-phospha-6-boratricyclo-hept-3- enes. A rational mechanism for this transformation is proposed and supported by DFT calculations.

Comments

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David Wilson is affiliated with Avondale College of Higher Education as a Conjoint Senior Lecturer.

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