Reactivity of a Phosphaalkyne with Pentaarylboroles
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Publication Date
2016-03-25
Avondale Authors
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Original
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Copyright © 2016 American Chemical Society
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Published Version
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Peer Reviewed
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Degree
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Abstract
The reactions of pentaarylboroles with 1-adamantylphosphaalkyne led to the formation of unique 1-phospha-6-boratricyclo-hept-3- enes. A rational mechanism for this transformation is proposed and supported by DFT calculations.
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Citation
Barnard, J. H., Yruegas, S., Couchman, S. A., Wilson, D. J., Dutton, J. L., & Martin, C. D. (2016). Reactivity of a phosphaalkyne with pentaarylboroles. Organometallics, 35(7), 929-931. doi:10.1021/acs.organomet.6b00123
Source Title
Organometallics
Series
International Standard Serial Number
0276-7333