Investigating the Ring Expansion Reaction of Pentaphenylborole and an Azide
| avondale-bepress.context-key | 6916447 | |
| avondale-bepress.submission-path | sci_math_papers/74 | |
| avondale.faculty | Science | |
| avondale.reporting.isPeerReviewed | Peer Reviewed | |
| avondale.reporting.version | Published Version | |
| dc.contributor.author | Martin, Caleb D. | |
| dc.contributor.author | Dutton, Jason L. | |
| dc.contributor.author | Wilson, David J. | |
| dc.contributor.author | Thompson, Trevor K. | |
| dc.contributor.author | Couchman, Shannon A. | |
| dc.date.accessioned | 2023-11-01T00:22:34Z | |
| dc.date.available | 2023-11-01T00:22:34Z | |
| dc.date.issued | 2014-10-11 | |
| dc.date.submitted | 2015-03-29T23:42:38Z | |
| dc.description.abstract | <p>The reaction between trimethylsilyl azide and pentaphenylborole was recently shown to produce the corresponding 1,2-azaborine. Investigating this transformation theoretically suggests that the reaction proceeds via coordination of the azide to the borole, rearrangement to a bicyclic species, and conversion to a kinetically favoured eightmembered BN3C4 heterocycle or expulsion of N2 to furnish the thermodynamically favoured 1,2-azaborine. The eight-membered species was structurally characterized as a borole adduct and represents an unusual analogue of cyclooctatetraene.</p> | |
| dc.identifier.citation | <p>Couchman, S. A., Thompson, T. K., Wilson, D. J., Dutton, J. L., & Martin, C. D. (2014). Investigating the ring expansion reaction of pentaphenylborole and an azide. <em>Chemical Communications, 50</em>(79), 11724-11726. doi:10.1039/C4CC04864D</p> | |
| dc.identifier.doi | https://doi.org/10.1039/C4CC04864D | |
| dc.identifier.issn | 1359-7345 | |
| dc.identifier.uri | https://research.avondale.edu.au/handle/1897/06916447 | |
| dc.language.iso | en_us | |
| dc.provenance | <p>This article was originally published as:</p> <p>Couchman, S. A., Thompson, T. K., Wilson, D. J., Dutton, J. L., & Martin, C. D. (2014). Investigating the ring expansion reaction of pentaphenylborole and an azide. <em>Chemical Communications, 50</em>(79), 11724-11726. doi:10.1039/C4CC04864D</p> <p>ISSN:1364-548X</p> | |
| dc.relation.ispartof | Chemical Communications | |
| dc.rights | <p>Due to copyright restrictions this article is unavailable for download.</p> <p>Published by the <a href="http://www.rsc.org/">Royal Society of Chemistry</a></p> | |
| dc.subject | reaction | |
| dc.subject | pentaphenylborole | |
| dc.title | Investigating the Ring Expansion Reaction of Pentaphenylborole and an Azide | |
| dc.type | Journal Article |