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Access to the Parent Tetrakis(pyridine)gold(III) Trication, Facile Formation of Rare Au(III) Terminal Hydroxides, and Preliminary Studies of Biological Properties

avondale-bepress.context-key9775938
avondale-bepress.submission-pathsci_math_papers/88
avondale.facultyScience
avondale.reporting.isPeerReviewedPeer Reviewed
avondale.reporting.versionPublished Version
dc.contributor.authorDutton, Jason L.
dc.contributor.authorBarnard, Peter J.
dc.contributor.authorHulett, Mark D.
dc.contributor.authorWilson, David J.
dc.contributor.authorHogan, Conor F.
dc.contributor.authorHaghighatbin, Mohammad A.
dc.contributor.authorRyan, Gemma F.
dc.contributor.authorCorbo, Robert
dc.date.accessioned2023-11-01T00:24:43Z
dc.date.available2023-11-01T00:24:43Z
dc.date.issued2016-03-21
dc.date.submitted2017-03-02T00:20:00Z
dc.description.abstract<p>In this paper we report on the use of [NO][BF4] to access tricationic tetrakis(pyridine)gold(III) from Au powder, a species inaccessible using the more traditional (tetrahydrothiophene)AuCl route. It is then demonstrated that this family of compounds can be used to access new terminal Au(III) hydroxides, a challenging class of compounds, and the first crystallographically characterized examples employing bidentate ligands. Finally, preliminary biological studies indicate good activity for derivatives featuring polydentate ligands against the HeLa and PC3 cell lines but also strong inhibition of primary HUVEC cells.</p>
dc.identifier.citation<p>Corbo, R., Ryan, G. F., Haghighatbin, M. A., Hogan, C. F., Wilson, D. J.,... Dutton, J. L. (2016). Access to the parent Tetrakis(pyridine)gold(III) Trication, Facile formation of Rare Au(III) Terminal Hydroxides, and preliminary studies of biological properties. <em>Inorganic Chemistry, 55</em>(6), 2830-2839. doi: 10.1021/acs.inorgchem.5b02667</p>
dc.identifier.doihttps://doi.org/10.1021/acs.inorgchem.5b02667
dc.identifier.issn1520-510X
dc.identifier.urihttps://research.avondale.edu.au/handle/1897/09775938
dc.language.isoen_us
dc.provenance<p>This article was originally published as:</p> <p>Corbo, R., Ryan, G. F., Haghighatbin, M. A., Hogan, C. F., Wilson, D. J.,... Dutton, J. L. (2016). Access to the parent Tetrakis(pyridine)gold(III) Trication, Facile formation of Rare Au(III) Terminal Hydroxides, and preliminary studies of biological properties. <em>Inorganic Chemistry, 55</em>(6), 2830-2839. doi: 10.1021/acs.inorgchem.5b02667</p> <p>ISSN:1520-510X</p>
dc.relation.ispartofInorganic Chemistry
dc.rights<p>Due to copyright restrictions this article is unavailable for download.</p> <p>Copyright © 2016 American Chemical Society</p>
dc.titleAccess to the Parent Tetrakis(pyridine)gold(III) Trication, Facile Formation of Rare Au(III) Terminal Hydroxides, and Preliminary Studies of Biological Properties
dc.typeJournal Article

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