Is the Perfluorinated Trityl Cation Worth a Revisit? A Theoretical Study on the Lewis Acidities and Stabilities of Highly Halogenated Trityl Derivatives
| avondale-bepress-to-dspace.faculty | Science | |
| avondale-bepress-to-dspace.peer_review_status | Peer reviewed before publication | |
| avondale-bepress.context-key | 6914667 | |
| avondale-bepress.submission-path | sci_math_papers/67 | |
| avondale.faculty | Science | |
| avondale.reporting.isPeerReviewed | Yes | |
| avondale.reporting.version | Published Version | |
| dc.contributor.author | Dutton, Jason L. | |
| dc.contributor.author | Wilson, David J. | |
| dc.contributor.author | Couchman, Shannon A. | |
| dc.date.accessioned | 2023-11-01T00:39:24Z | |
| dc.date.available | 2023-11-01T00:39:24Z | |
| dc.date.issued | 2014-06-10 | |
| dc.date.submitted | 2015-03-29T01:48:50Z | |
| dc.description.abstract | <p>The relative Lewis acidities of a series of known, unknown and observed but unstable halogenated derivatives of the trityl cation have been probed in a computational study. The Lewis acidity was investigated from hydride, fluoride and methide affinities. The results indicate that the perhalogen-ated trityl cation [C(C6F5)3]+ is a desirable synthetic target, especially in the modern age of weakly coordinating anions. Our results also indicate that the stable [C(C6Cl5)3]+ cation may be an equally interesting Lewis acid.</p> | |
| dc.identifier.citation | <p>Couchman, S. A., Wilson, D. J., & Dutton, J. L. (2014). Is the perfluorinated trityl cation worth a revisit? A theoretical study on the lewis acidities and stabilities of highly halogenated trityl derivatives. <em>European Journal of Organic Chemistry, 2014</em>(18), 3902-3908. doi:10.1002/ejoc.201402263</p> | |
| dc.identifier.doi | https://doi.org/10.1002/ejoc.201402263 | |
| dc.identifier.issn | 1434-193X | |
| dc.identifier.uri | https://research.avondale.edu.au/handle/123456789/06914667 | |
| dc.language.iso | en_us | |
| dc.provenance | <p>This article was originally published as:</p> <p>Couchman, S. A., Wilson, D. J., & Dutton, J. L. (2014). Is the perfluorinated trityl cation worth a revisit? A theoretical study on the lewis acidities and stabilities of highly halogenated trityl derivatives. <em>European Journal of Organic Chemistry, 2014</em>(18), 3902-3908. doi:10.1002/ejoc.201402263</p> <p>ISSN:1099-0690</p> | |
| dc.relation.ispartof | European Journal of Organic Chemistry | |
| dc.rights | <p>Due to copyright restrictions this article is unavailable for download.</p> | |
| dc.subject | Perfluorination | |
| dc.subject | Lewis acids | |
| dc.subject | Carbocations | |
| dc.subject | Density functional calculations | |
| dc.title | Is the Perfluorinated Trityl Cation Worth a Revisit? A Theoretical Study on the Lewis Acidities and Stabilities of Highly Halogenated Trityl Derivatives | |
| dc.type | Journal Article |