Metal Complexes with di(N-heterocyclic carbene) Ligands Bearing a Rigid Ortho-, Meta or Para-phenylene Bridge

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avondale-bepress-to-dspace.facultyScience
avondale-bepress-to-dspace.peer_review_statusPeer reviewed before publication
avondale-bepress.abstract<p>Three novel dinuclear bis-dicarbene silver(I) complexes of general formula [Ag2(MeIm-phenylene-MeIm)2] (PF6)2 (Im = imidazol-2-ylidene) were synthesized. The corresponding copper(I) and gold(I) complexes were obtained by transmetalation of the di(N-heterocyclic carbene) ligand from the silver(I) species, and both coordination geometry and stoichiometry are maintained for all three group 11 metals as expected. The photophysical properties of the Ag(I) and Au(I) complexes were also investigated and discussed; in particular the most strongly emitting complex was also studied via DFT calculations. In addition, the ruthenium(II) and iridium(III) complexes [RuCl(MeIm-(o-phenylene)-MeIm)(p-cym)](PF6) and [IrClCp*- (MeIm-(o-phenylene)-MeIm)](PF6) were prepared and shown to present in these cases a chelating coordination of the di(N-heterocyclic carbene) ligand.</p>
avondale-bepress.articleid1083
avondale-bepress.authorsMarco Monticelli
avondale-bepress.authorsCristina Tubaro
avondale-bepress.authorsMarco Baron
avondale-bepress.authorsMarino Basato
avondale-bepress.authorsPaolo Sgarbossa
avondale-bepress.authorsClaudia Graiff
avondale-bepress.authorsGianluca Accorsi
avondale-bepress.authorsThomas P Pell
avondale-bepress.authorsDavid J Wilson
avondale-bepress.authorsPeter J Barnard
avondale-bepress.context-key9759004
avondale-bepress.coverpage-urlhttps://research.avondale.edu.au/sci_math_papers/84
avondale-bepress.document-typearticle
avondale-bepress.field.author_faculty_disciplineScience
avondale-bepress.field.avon_earlyonline2016-05-06T00:00:00-07:00
avondale-bepress.field.comments<p>Due to copyright restrictions this article is unavailable for download.</p> <p>Copyright © 2016 Royal Society of Chemistry</p>
avondale-bepress.field.custom_citation<p>Monticelli, M., Tubaro, C., Baron, M., Basato, M., Sgarbossa, P... Barnard, P. J. (2016). Metal complexes with di(N-heterocyclic carbene) ligands bearing a rigid ortho-, meta or para-phenylene bridge. <em>Dalton Transactions, 45</em>(23), 9540-9552. doi: 10.1039/C6DT01129B</p>
avondale-bepress.field.doihttps://doi.org/10.1039/C6DT01129B
avondale-bepress.field.email_boxtrue
avondale-bepress.field.embargo_date2017-07-27T00:00:00Z
avondale-bepress.field.field_of_education01 Natural and Physical Sciences
avondale-bepress.field.for030701 Quantum Chemistry
avondale-bepress.field.issn1477-9226
avondale-bepress.field.issue_number23
avondale-bepress.field.journalDalton Transactions
avondale-bepress.field.page_numbers9540-9552
avondale-bepress.field.peer_reviewBefore publication
avondale-bepress.field.publication_date2016-06-21T00:00:00Z
avondale-bepress.field.source_fulltext_urlhttps://doi.org/10.1039/C6DT01129B
avondale-bepress.field.source_publication<p>This article was originally published as:</p> <p>Monticelli, M., Tubaro, C., Baron, M., Basato, M., Sgarbossa, P... Barnard, P. J. (2016). Metal complexes with di(N-heterocyclic carbene) ligands bearing a rigid ortho-, meta or para-phenylene bridge. <em>Dalton Transactions, 45</em>(23), 9540-9552. doi: 10.1039/C6DT01129B</p> <p>ISSN: 1477-9226</p>
avondale-bepress.field.staff_classificationConjoint
avondale-bepress.field.volume_number45
avondale-bepress.label84
avondale-bepress.publication-date2016-06-21T00:00:00Z
avondale-bepress.publication-titleScience and Mathematics Papers and Journal Articles
avondale-bepress.statepublished
avondale-bepress.submission-date2017-02-27T19:48:00Z
avondale-bepress.submission-pathsci_math_papers/84
avondale-bepress.titleMetal Complexes with di(N-heterocyclic carbene) Ligands Bearing a Rigid Ortho-, Meta or Para-phenylene Bridge
avondale-bepress.typearticle
dc.contributor.authorBarnard, Peter J.
dc.contributor.authorWilson, David J.
dc.contributor.authorPell, Thomas P.
dc.contributor.authorAccorsi, Gianluca
dc.contributor.authorGraiff, Claudia
dc.contributor.authorSgarbossa, Paolo
dc.contributor.authorBasato, Marino
dc.contributor.authorBaron, Marco
dc.contributor.authorTubaro, Cristina
dc.contributor.authorMonticelli, Marco
dc.date.accessioned2023-11-01T00:24:42Z
dc.date.available2023-11-01T00:24:42Z
dc.date.issued2016-06-21
dc.date.submitted2017-02-27T19:48:00Z
dc.description.abstract<p>Three novel dinuclear bis-dicarbene silver(I) complexes of general formula [Ag2(MeIm-phenylene-MeIm)2] (PF6)2 (Im = imidazol-2-ylidene) were synthesized. The corresponding copper(I) and gold(I) complexes were obtained by transmetalation of the di(N-heterocyclic carbene) ligand from the silver(I) species, and both coordination geometry and stoichiometry are maintained for all three group 11 metals as expected. The photophysical properties of the Ag(I) and Au(I) complexes were also investigated and discussed; in particular the most strongly emitting complex was also studied via DFT calculations. In addition, the ruthenium(II) and iridium(III) complexes [RuCl(MeIm-(o-phenylene)-MeIm)(p-cym)](PF6) and [IrClCp*- (MeIm-(o-phenylene)-MeIm)](PF6) were prepared and shown to present in these cases a chelating coordination of the di(N-heterocyclic carbene) ligand.</p>
dc.description.versionBefore publication
dc.identifier.citation<p>Monticelli, M., Tubaro, C., Baron, M., Basato, M., Sgarbossa, P... Barnard, P. J. (2016). Metal complexes with di(N-heterocyclic carbene) ligands bearing a rigid ortho-, meta or para-phenylene bridge. <em>Dalton Transactions, 45</em>(23), 9540-9552. doi: 10.1039/C6DT01129B</p>
dc.identifier.doihttps://doi.org/10.1039/C6DT01129B
dc.identifier.issn1477-9226
dc.identifier.urihttps://research.avondale.edu.au/handle/123456789/09759004
dc.language.isoen_us
dc.provenance<p>This article was originally published as:</p> <p>Monticelli, M., Tubaro, C., Baron, M., Basato, M., Sgarbossa, P... Barnard, P. J. (2016). Metal complexes with di(N-heterocyclic carbene) ligands bearing a rigid ortho-, meta or para-phenylene bridge. <em>Dalton Transactions, 45</em>(23), 9540-9552. doi: 10.1039/C6DT01129B</p> <p>ISSN: 1477-9226</p>
dc.rights<p>Due to copyright restrictions this article is unavailable for download.</p> <p>Copyright © 2016 Royal Society of Chemistry</p>
dc.titleMetal Complexes with di(N-heterocyclic carbene) Ligands Bearing a Rigid Ortho-, Meta or Para-phenylene Bridge
dc.typeJournal Article
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