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Chemiluminescence Detection with Water-Soluble Iridium(III) Complexes Containing a Sulfonatefunctionalised Ancillary Ligand

avondale-bepress.context-key6915739
avondale-bepress.submission-pathsci_math_papers/70
avondale.facultyScience
avondale.reporting.isPeerReviewedPeer Reviewed
avondale.reporting.versionPublished Version
dc.contributor.authorFrancis, Paul S.
dc.contributor.authorZhou, Ming
dc.contributor.authorHockey, Samantha C.
dc.contributor.authorAltimari, Jarrad M.
dc.contributor.authorHenderson, Luke C.
dc.contributor.authorBarnett, Neil W.
dc.contributor.authorWilson, David J.
dc.contributor.authorDoeven, Egan H.
dc.contributor.authorBarbante, Gregory J.
dc.contributor.authorSpilstead, Kara B.
dc.contributor.authorTruong, Josephine
dc.date.accessioned2023-11-01T00:22:33Z
dc.date.available2023-11-01T00:22:33Z
dc.date.issued2014-11-21
dc.date.submitted2015-03-29T22:37:20Z
dc.description.abstract<p>The chemiluminescence from four cyclometalated iridium(III) complexes containing an ancillary bathophenanthroline-disulfonate ligand exhibited a wide range of emission colours (green to red), and in some cases intensities that are far greater than the commonly employed benchmark reagent, [Ru(bpy)3]2+. A similar complex incorporating a sulfonated triazolylpyridine-based ligand enabled the emission to be shifted into the blue region of the spectrum, but the responses with this complex were relatively poor. DFT calculations of electronic structure and emission spectra support the experimental findings.</p>
dc.identifier.citation<p>Truong, J., Spilstead, K. B., Barbante, B. J., Doeven, E. H., Wilson, D. J.,... Francis, P. S. (2014). Chemiluminescence detection with water-soluble iridium(III) complexes containing a sulfonatefunctionalised ancillary ligand. <em>Analyst, 139</em>(22), 6028-6035. doi:10.1039/c4an01366b</p>
dc.identifier.doihttps://doi.org/10.1039/C4AN01366B
dc.identifier.issn0003-2654
dc.identifier.urihttps://research.avondale.edu.au/handle/1897/06915739
dc.language.isoen_us
dc.provenance<p>This article was originally published as:</p> <p>Truong, J., Spilstead, K. B., Barbante, B. J., Doeven, E. H., Wilson, D. J.,... Francis, P. S. (2014). Chemiluminescence detection with water-soluble iridium(III) complexes containing a sulfonatefunctionalised ancillary ligand. <em>Analyst, 139</em>(22), 6028-6035. doi:10.1039/c4an01366b</p> <p>ISSN:1364-5528</p>
dc.relation.ispartofAnalyst
dc.rights<p>Used by permission: the author(s).</p> <p>Published by The Royal Society of Chemistry.</p>
dc.rights.licensehttp://creativecommons.org/licenses/by/3.0/
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/
dc.titleChemiluminescence Detection with Water-Soluble Iridium(III) Complexes Containing a Sulfonatefunctionalised Ancillary Ligand
dc.typeJournal Article

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