Browsing by Author "Aprile, Antonio"
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Item The First Bismuth–NHC Complexes(2014-01-14) Dutton, Jason L.; Wilson, David J.; Vin Tan, Kel; Corbo, Robert; Aprile, AntonioThe synthesis, isolation and crystallographic characterization of the first N-heterocyclic carbene adducts of bismuth is reported, by direct reaction of the Dipp2NHC (Dipp = 2,6-diisopropylphenyl) or iPr2(Me2)- NHC with BiCl3. This represents the last non-radioactive element from groups 13–17 for which an NHC– element fragment remained unreported.