Singlet Levels of the NV− Centre in Diamond

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avondale-bepress-to-dspace.facultyScience
avondale-bepress-to-dspace.licensehttp://creativecommons.org/licenses/by/3.0/
avondale-bepress-to-dspace.peer_review_statusPeer reviewed before publication
avondale-bepress.abstract<p>The characteristic transition of the NV− centre at 637 nm is between 3A 2 and E 3 triplet states. There are also intermediate A 1 1 and E 1 singlet states, and the infrared transition at 1042 nmbetween these singlets is studied here using uniaxial stress. The stress shift and splitting parameters are determined, and the physical interaction giving rise to the parameters is considered within the accepted electronic model of the centre. It is established that this interaction for the infrared transition is due to a modification of electron–electron Coulomb repulsion interaction. This is in contrast to the visible 637 nm transition where shifts and splittings arise from modification to the one-electron Coulomb interaction. It is also established that a dynamic Jahn–Teller interaction is associated with the singlet E 1 state, which gives rise to a vibronic level 115 cm−1 above the E 1 electronic state. Arguments associated with this level are used to provide experimental confirmation that the A 1 1 is the upper singlet level and E 1 is the lower singlet level.</p>
avondale-bepress.articleid1057
avondale-bepress.authorsLachlan J Rogers
avondale-bepress.authorsMarcus W Doherty
avondale-bepress.authorsMichael S Barson
avondale-bepress.authorsS Onoda
avondale-bepress.authorsT Ohshima
avondale-bepress.authorsNeil B Manson
avondale-bepress.context-key6624988
avondale-bepress.coverpage-urlhttps://research.avondale.edu.au/sci_math_papers/58
avondale-bepress.document-typearticle
avondale-bepress.field.author_faculty_disciplineScience
avondale-bepress.field.comments<p>Used by permission: the author(s).</p>
avondale-bepress.field.custom_citation<p>Rogers, L. J., Doherty, M. W., Barson, M. S. J., Ohshima, T., & Manson, N. B. (2015). Singlet levels of the NV− centre in diamond. <em>New Journal of Physics, 17</em>(1), 013048. doi:10.1088/1367-2630/17/1/013048</p>
avondale-bepress.field.distribution_licensehttp://creativecommons.org/licenses/by/3.0/
avondale-bepress.field.doihttps://doi.org/10.1088/1367-2630/17/1/013048
avondale-bepress.field.embargo_date2015-02-08T00:00:00Z
avondale-bepress.field.field_of_education01 Natural and Physical Sciences
avondale-bepress.field.for010503 Mathematical Aspects of Classical Mechanics, Quantum Mechanics and Quantum Information Theory
avondale-bepress.field.issn1367-2630
avondale-bepress.field.issue_number1
avondale-bepress.field.journalNew Journal of Physics
avondale-bepress.field.page_numbers013048
avondale-bepress.field.peer_reviewBefore publication
avondale-bepress.field.publication_date2015-01-27T00:00:00Z
avondale-bepress.field.reportable_itemsC1
avondale-bepress.field.source_publication<p>This article was originally published as:</p> <p>Rogers, L. J., Doherty, M. W., Barson, M. S. J., Ohshima, T., & Manson, N. B. (2015). Singlet levels of the NV− centre in diamond. <em>New Journal of Physics, 17</em>(1), 1-12. doi:10.1088/1367-2630/17/1/013048</p> <p>ISSN: 1367-2630</p>
avondale-bepress.field.staff_classificationPermanent
avondale-bepress.field.volume_number17
avondale-bepress.fulltext-urlhttps://research.avondale.edu.au/cgi/viewcontent.cgi?article=1057&amp;context=sci_math_papers&amp;unstamped=1
avondale-bepress.keywordsnitrogen-vacancy
avondale-bepress.keywordsdiamond
avondale-bepress.keywordsuniaxial stress
avondale-bepress.keywordsinfrared emission
avondale-bepress.keywordsspin polarization
avondale-bepress.keywordscolour centre
avondale-bepress.label58
avondale-bepress.publication-date2015-01-27T00:00:00Z
avondale-bepress.publication-titleScience and Mathematics Papers and Journal Articles
avondale-bepress.statepublished
avondale-bepress.submission-date2015-02-08T18:20:28Z
avondale-bepress.submission-pathsci_math_papers/58
avondale-bepress.titleSinglet Levels of the NV− Centre in Diamond
avondale-bepress.typearticle
dc.contributor.authorManson, Neil B.
dc.contributor.authorOhshima, T
dc.contributor.authorOnoda, S
dc.contributor.authorBarson, Michael S.
dc.contributor.authorDoherty, Marcus W.
dc.contributor.authorRogers, Lachlan J.
dc.date.accessioned2023-11-01T00:39:18Z
dc.date.available2023-11-01T00:39:18Z
dc.date.issued2015-01-27
dc.date.submitted2015-02-08T18:20:28Z
dc.description.abstract<p>The characteristic transition of the NV− centre at 637 nm is between 3A 2 and E 3 triplet states. There are also intermediate A 1 1 and E 1 singlet states, and the infrared transition at 1042 nmbetween these singlets is studied here using uniaxial stress. The stress shift and splitting parameters are determined, and the physical interaction giving rise to the parameters is considered within the accepted electronic model of the centre. It is established that this interaction for the infrared transition is due to a modification of electron–electron Coulomb repulsion interaction. This is in contrast to the visible 637 nm transition where shifts and splittings arise from modification to the one-electron Coulomb interaction. It is also established that a dynamic Jahn–Teller interaction is associated with the singlet E 1 state, which gives rise to a vibronic level 115 cm−1 above the E 1 electronic state. Arguments associated with this level are used to provide experimental confirmation that the A 1 1 is the upper singlet level and E 1 is the lower singlet level.</p>
dc.description.versionBefore publication
dc.identifier.citation<p>Rogers, L. J., Doherty, M. W., Barson, M. S. J., Ohshima, T., & Manson, N. B. (2015). Singlet levels of the NV− centre in diamond. <em>New Journal of Physics, 17</em>(1), 013048. doi:10.1088/1367-2630/17/1/013048</p>
dc.identifier.doihttps://doi.org/10.1088/1367-2630/17/1/013048
dc.identifier.issn1367-2630
dc.identifier.urihttps://research.avondale.edu.au/handle/123456789/06624988
dc.language.isoen_us
dc.provenance<p>This article was originally published as:</p> <p>Rogers, L. J., Doherty, M. W., Barson, M. S. J., Ohshima, T., & Manson, N. B. (2015). Singlet levels of the NV− centre in diamond. <em>New Journal of Physics, 17</em>(1), 1-12. doi:10.1088/1367-2630/17/1/013048</p> <p>ISSN: 1367-2630</p>
dc.rights<p>Used by permission: the author(s).</p>
dc.rights.licensehttp://creativecommons.org/licenses/by/3.0/
dc.subjectnitrogen-vacancy
dc.subjectdiamond
dc.subjectuniaxial stress
dc.subjectinfrared emission
dc.subjectspin polarization
dc.subjectcolour centre
dc.titleSinglet Levels of the NV− Centre in Diamond
dc.typeJournal Article
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